Hydrogen shifts: Difference between revisions
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{{Final | {{Final | ||
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|def=[[wikipedia:Sigmatropic reaction|Sigmatropic reactions]] of [[ion]]s in which the [[wikipedia:Sigma bond|?-bonds]] broken and formed involve [[wikipedia:hydrogen|hydrogen]] atoms, and are subject to the [[wikipedia: | |def=[[wikipedia:Sigmatropic reaction|Sigmatropic reactions]] of [[ion]]s in which the [[wikipedia:Sigma bond|?-bonds]] broken and formed involve [[wikipedia:hydrogen|hydrogen]] atoms, and are subject to the [[wikipedia:Woodward-Hoffmann rules|Woodward-Hofmann rules]] resulting from [[wikipedia:Molecular orbital|orbital]] [[wikipedia:Molecular symmetry|symmetry]] considerations. | ||
|rel= | |rel= | ||
|ref=R. B. Woodward, R. Hoffmann. The Conservation of Orbital Symmetry, Verlag Chemie Academic Press (2004). | |ref=R. B. Woodward, R. Hoffmann. The Conservation of Orbital Symmetry, Verlag Chemie Academic Press (2004). | ||
}} | }} | ||
Latest revision as of 11:36, 19 March 2021
| IUPAC RECOMMENDATIONS 2013 |
| Hydrogen shifts |
|---|
| Sigmatropic reactions of ions in which the ?-bonds broken and formed involve hydrogen atoms, and are subject to the Woodward-Hofmann rules resulting from orbital symmetry considerations. |
| Related Term(s): |
| Reference(s):
R. B. Woodward, R. Hoffmann. The Conservation of Orbital Symmetry, Verlag Chemie Academic Press (2004). |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
