Rice Ramsperger Kassel theory: Difference between revisions

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{{Final
#REDIRECT [[Rice-Ramsperger-Kassel (RRK) theory]]
|acronym=([[RRK]])
|def=Statistical theory of unimolecular reaction rates of gas-phase molecular species that is equivalent to the quasi-equilibrium theory, but with the added consideration that the effects of gas-phase collisions in activation to and deactivation from the transition state are taken into account.
 
:Note: Elimination of most of the simplifying assumptions led to development of the [[RiceRamspergerKasselMarcus (RRKM) theory]].
|rel=
|ref=Revised from
 
{{gb}}
 
using additional information from
 
T. Baercor, P. M. Mayer. J. Am. Soc. Mass Spectrom. 8, 103 (1997). (http://dx.doi.org/10.1016/S1044-0305(96)00212-7 )
 
O. K. Rice, H. C. Ramsperger. J. Am. Chem. Soc. 50, 617 (1928). (http://dx.doi.org/10.1021/ja01390a002 )
 
L. S. Kassel. J. Phys. Chem. 32, 225 (1928). (http://dx.doi.org/10.1021/j150284a007 )
}}

Latest revision as of 16:47, 8 June 2025

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