Charge-transfer reaction (in mass spectrometry): Difference between revisions
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== | {{Final | ||
|acronym= | |||
|def='''Charge-transfer reaction''' (in mass spectrometry) | |||
'''[[charge exchange reaction]]''' | |||
Reaction of an [[ion]] with a neutral or collision partner ion in which some or all of the charge on the [[reactant ion]] is transferred to the neutral or collision partner ion. | |||
|rel= | |||
|ref=Revised from | |||
{{obgb}} | |||
M- + X | using additional information from | ||
P. S. Rudolph, C. E. Melton. J. Chem. Phys. 32, 586 (1960). (http://dx.doi.org/10.1063/1.1730740 ) | |||
}} | |||
<!-- Orange Book --> | |||
{{orange| | |||
An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M<sup>2+,</sup> M<sup>+</sup> and M<sup>-</sup> with a neutral species X are categorized in terms of the above definitions as follows: | |||
M<sup>2+</sup> + X → M<sup>+</sup> + X<sup>+</sup> (Partial charge transfer) | |||
M<sup>+</sup> + X → M<sup>2+</sup> + X + e ([[Charge Stripping Reaction|Charge stripping]]) | |||
M<sup>-</sup> + X → M<sup>+</sup> + X + 2e ([[Charge Stripping Reaction|Charge stripping]] & [[Charge Inversion Reaction|charge inversion]]) | |||
These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | ||
}} | |||
<!-- Gold Book --> | |||
{{gold| | |||
http://goldbook.iupac.org/C01005.html | |||
An ion/neutral species reaction wherein the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Considering some of the possible reactions of ions M2+, M+ and M? with a neutral species X, these would be further categorized as follows: | |||
M<sup>2+</sup> + X → M<sup>+</sup> + X<sup>+</sup> (Partial charge transfer) | |||
M<sup>+</sup> + X → M<sup>2+</sup> + X + e ([[Charge Stripping Reaction|Charge stripping]]) | |||
M<sup>-</sup> + X → M<sup>+</sup> + X + 2e ([[Charge Stripping Reaction|Charge stripping]] & [[Charge Inversion Reaction|charge inversion]]) | |||
All are ion/neutral species reactions and also charge permutation reactions. | |||
Source: PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1555 | |||
}} | |||
[[Category:Reactions]] | |||
[[Category:Orange Book term]] | |||
Latest revision as of 16:05, 25 October 2013
| IUPAC RECOMMENDATIONS 2013 |
| Charge-transfer reaction (in mass spectrometry) |
|---|
| Charge-transfer reaction (in mass spectrometry)
Reaction of an ion with a neutral or collision partner ion in which some or all of the charge on the reactant ion is transferred to the neutral or collision partner ion. |
| Related Term(s): |
| Reference(s):
Revised from IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979. Compiled by J. Inczdy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000). IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. using additional information from P. S. Rudolph, C. E. Melton. J. Chem. Phys. 32, 586 (1960). (http://dx.doi.org/10.1063/1.1730740 ) |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
Orange Book
| ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
| Charge-transfer reaction (in mass spectrometry) |
|---|
|
An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows: M2+ + X → M+ + X+ (Partial charge transfer) M+ + X → M2+ + X + e (Charge stripping) M- + X → M+ + X + 2e (Charge stripping & charge inversion) These are all ion/neutral species reactions and also charge permutation reactions. |
| IUPAC 1997 Orange Book Chapter 12 |
| Index of Orange Book Terms |
Gold Book
| GOLD BOOK DEFINITION
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). |
| Charge-transfer reaction (in mass spectrometry) |
|---|
|
http://goldbook.iupac.org/C01005.html An ion/neutral species reaction wherein the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Considering some of the possible reactions of ions M2+, M+ and M? with a neutral species X, these would be further categorized as follows: M2+ + X → M+ + X+ (Partial charge transfer) M+ + X → M2+ + X + e (Charge stripping) M- + X → M+ + X + 2e (Charge stripping & charge inversion) All are ion/neutral species reactions and also charge permutation reactions. Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1555 |
| IUPAC Gold Book |
| Index of Gold Book Terms |
