Collisionally activated dissociation: Difference between revisions
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|acronym=(CAD) | |||
|def=See [[collision-induced dissociation]] (CID). | |||
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An ion/neutral species process wherein excitation of a projectile ion of high translational energy is brought about by the same mechanism as in [[collision-induced dissociation]]. | An ion/neutral species process wherein excitation of a projectile ion of high translational energy is brought about by the same mechanism as in [[collision-induced dissociation]]. | ||
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{{cad_cid}} | |||
[[ | ==External links== | ||
*F.W. McLafferty, P.F. Bente, R. Kornfeld, S.-C. Tsai, I. Howe, Metastable ion characteristics. XXII. [[Collisional activation spectra]] of organic ions, J. Am. Chem. Soc. 95 (1973) 21202129. {{doi}}10.1021/ja00788a007. | |||
*K. Levsen, H. Schwarz, [[Collisional activation mass spectrometry]] - A New Probe for Determining the Structure of Ions in the Gas Phase, Angew. Chem. Int. Ed. Engl. 15 (1976) 509519. {{doi}}10.1002/anie.197605091. | |||
*S.A. McLuckey, Principles of collisional activation in analytical mass spectrometry, J. Am. Soc. Mass Spectrom. 3 (1992) 599614. {{doi}}10.1016/1044-0305(92)85001-Z. | |||
*L.S. Kassel, The Dynamics of Unimolecular Reactions, Chem. Rev. 10 (1932) 1125. {{doi}}10.1021/cr60035a002 | |||
[[Category:Fragmentation]] | |||
[[Category:Reactions]] | [[Category:Reactions]] | ||
[[Category:Orange Book term]] | |||
{{DEFAULTSORT:Collisionally Activated Dissociation}} | |||
Latest revision as of 21:55, 21 August 2019
| IUPAC RECOMMENDATIONS 2013 |
| Collisionally activated dissociation (CAD) |
|---|
| See collision-induced dissociation (CID). |
| Related Term(s): |
| Reference(s): |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
Orange Book
| ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
| Collisionally activated dissociation |
|---|
|
An ion/neutral species process wherein excitation of a projectile ion of high translational energy is brought about by the same mechanism as in collision-induced dissociation. |
| IUPAC 1997 Orange Book Chapter 12 |
| Index of Orange Book Terms |
| QUOTED TEXT FROM IUPAC RECOMMENDATIONS 2013 |
| The terms collision-induced dissociation (CID) and collisionally activated dissociation (CAD) are both recommended by IUPAC [1] and are used interchangeably in recent literature. They are listed as synonyms in this document. |
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
|---|
External links
- F.W. McLafferty, P.F. Bente, R. Kornfeld, S.-C. Tsai, I. Howe, Metastable ion characteristics. XXII. Collisional activation spectra of organic ions, J. Am. Chem. Soc. 95 (1973) 21202129. http://dx.doi.org/10.1021/ja00788a007.
- K. Levsen, H. Schwarz, Collisional activation mass spectrometry - A New Probe for Determining the Structure of Ions in the Gas Phase, Angew. Chem. Int. Ed. Engl. 15 (1976) 509519. http://dx.doi.org/10.1002/anie.197605091.
- S.A. McLuckey, Principles of collisional activation in analytical mass spectrometry, J. Am. Soc. Mass Spectrom. 3 (1992) 599614. http://dx.doi.org/10.1016/1044-0305(92)85001-Z.
- L.S. Kassel, The Dynamics of Unimolecular Reactions, Chem. Rev. 10 (1932) 1125. http://dx.doi.org/10.1021/cr60035a002
