Ambient ionization techniques: Difference between revisions

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==Classification==
==Classification==
From {{doi}}10.1021/cr300309q (Monge, M. E.; Harris, G. A.; Dwivedi, P.; Fernandez, F. M. Mass Spectrometry: Recent Advances in Direct Open Air Surface Sampling/Ionization. ''Chem. Rev.'' '''2013''', ''113'', 22692308)


===Extraction===
===Extraction===
"One-step techniques where desorption occurs by solid?liquid extraction processes dynamically followed by ESI, APPI, sonic spray, or CI ion production mechanisms"


===Plasma===
===Plasma===
"One-step plasma-based techniques involving thermal or chemical sputtering desorption of neutrals working in parallel with chemical ionization mechanisms"


===Two step===
===Two step===
"Two-step techniques involving thermal desorption or mechanical ablation followed by secondary ionization"


===Laser===
===Laser===
"Two-step techniques involving laser desorption/ablation followed by secondary ionization"


===Acoustic===
===Acoustic===
"Two-step acoustic desorption methods"


===Multimode===
===Multimode===
"Multimode techniques involving two of the principles in previous categories"


===Other===
===Other===
"One-of-a-kind techniques that do not fit into previous categories"


==References==
==References==

Revision as of 15:06, 9 July 2014

Tabulated ambient ionization techniques. Click the header box to sort.

Acronym Technique Material Removal Ionization Classification Reference
ASAP Atmospheric pressure solids analysis probe Heat Chemical ionization #Plasma http://dx.doi.org/10.1021/ac051470k
APTDI Atmospheric pressure thermal desorption/ionization Heat #Plasma
BADCI Beta electron-assisted direct chemical ionization Heat Metastable chemical ionization #Two step http://dx.doi.org/10.1039/B909072J
DAPCI Desorption atmospheric pressure chemical ionization Heat Chemical ionization #Plasma http://dx.doi.org/10.1039/B418697D
DAPPI Desorption atmospheric pressure photoionization Heat Photoionization #Extraction http://dx.doi.org/10.1021/ac071152g
DART Direct analysis in real time Heat Metastable chemical ionization #Plasma http://dx.doi.org/10.1021/ac050162j
DBDI Dielectric barrier discharge ionization Heat Metastable chemical ionization #Plasma http://dx.doi.org/10.1016/j.jasms.2007.07.027
DCBI Desorption corona beam ionization Heat Metastable chemical ionization #Plasma http://dx.doi.org/10.1039/B922616H
DCI Desorption chemical ionization Heat Chemical ionization #Plasma
DEMI Desorption electrospray/metastable-induced ionization Solvent extraction Electrospray/Metastable chemical ionization #Multimode


http://dx.doi.org/10.1021/ac9014098
DESI Desorption Electrospray Ionization Liquid extraction Electrospray #Extraction
DICE Desorption ionization by charge exchange Liquid extraction #Extraction
EASI Easy ambient sonic-spray ionization Liquid extraction Droplet evaporation #Extraction http://dx.doi.org/10.1021/ac701960q
EESI Extractive electrospray ionization Aerosol extraction Electrospray #Two step http://dx.doi.org/10.1039/b602614a
ELDI Electrospray laser desorption ionization Laser Electrospray #Laser http://dx.doi.org/10.1002/rcm.3011
HAPGDI Helium atmospheric pressure glow discharge ionization #Plasma
IR-LAMICI Infrared laser ablation metastable-induced chemical ionization Laser Metastable chemical ionization #Laser http://dx.doi.org/10.1021/ac902905v
LADESI Laser assisted desorption electrospray ionization Laser Electrospray #Laser http://dx.doi.org/10.1039/b715146b
LAESI Laser ablation electrospray ionization Laser Electrospray #Laser http://dx.doi.org/10.1021/ac071181r
LA-FAPA Laser ablation flowing atmospheric pressure afterglow Laser Plasma #Laser http://dx.doi.org/10.1021/ac801594u
LA-ICP Laser ablation inductively coupled plasma Laser Plasma #Laser
LDESI Laser desorption electrospray ionization Laser Electrospray #Laser http://dx.doi.org/
LDI Laser desorption ionization Laser #Other
LEMS Laser electrospray mass spectrometry Laser Electrospray #Laser http://dx.doi.org/10.1002/rcm.4226
LESA Liquid extraction surface analysis Liquid microjunction Electrospray #Extraction
LIAD-ESI Laser-induced acoustic desorption-electrospray ionization Laser Electrospray #Acoustic http://dx.doi.org/10.1021/ac800896y
LMJ-SSP Liquid microjunction-surface sampling probe Liquid microjunction Electrospray #Extraction http://dx.doi.org/10.1021/ac901098d
LSI Laser spray ionization Laser Droplet evaporation #Other http://dx.doi.org/10.1074/mcp.M900527-MCP200
LTP Low temperature plasma Heat Metastable chemical ionization #Plasma http://dx.doi.org/10.1021/ac801641a
MAII Matrix-assisted inlet ionization Aerosol Droplet evaporation #Other http://dx.doi.org/10.1021/ac102339y
MALDESI Matrix-assisted laser desorption electrospray ionization Laser Electrospray #Laser http://dx.doi.org/10.1016/j.jasms.2006.08.003
nano-DESI Nanospray desorption electrospray ionization Liquid microjunction Electrospray #Extraction http://dx.doi.org/10.1039/C0AN00312C
ND-EESI Neutral desorption extractive electrospray ionization Gas Electrospray #Two step http://dx.doi.org/10.1002/jms.1282
PADI Plasma-assisted desorption ionization Heat Metastable chemical ionization #Plasma http://dx.doi.org/10.1021/ac070109q
PESI Probe electrospray ionization Solid extraction Electrospray #Two step http://dx.doi.org/10.1002/rcm.3201
PS Paper spray Solid extraction Electrospray http://dx.doi.org/10.1021/ac902854g
RADIO Radiofrequency acoustic desorption and ionization Acoustic Electrospray #Acoustic http://dx.doi.org/10.1016/j.jasms.2008.11.024
RASTIR Remote analyte sampling transport and ionization relay Gas Electrospray http://dx.doi.org/10.1021/ac800289f
REIMS Rapid evaporative ionization mass spectrometry Heat Charge separation #Other http://dx.doi.org/10.1002/anie.200902546
SACI Surface activated chemical ionization Heat Chemical ionization http://dx.doi.org/10.2174/138620709787315427
SAII Solvent-assisted inlet ionization Heat Droplet evaporation #Other http://dx.doi.org/10.1021/ac201982r
SPAMS Single-particle aerosol mass spectrometry Aerosol Laser desorption ionization #Other http://dx.doi.org/10.1021/ac901208h
TM-DESI Transmission mode desorption electrospray ionization Liquid extraction Electrospray #Extraction

Classification

From http://dx.doi.org/10.1021/cr300309q (Monge, M. E.; Harris, G. A.; Dwivedi, P.; Fernandez, F. M. Mass Spectrometry: Recent Advances in Direct Open Air Surface Sampling/Ionization. Chem. Rev. 2013, 113, 22692308)

Extraction

"One-step techniques where desorption occurs by solid?liquid extraction processes dynamically followed by ESI, APPI, sonic spray, or CI ion production mechanisms"

Plasma

"One-step plasma-based techniques involving thermal or chemical sputtering desorption of neutrals working in parallel with chemical ionization mechanisms"

Two step

"Two-step techniques involving thermal desorption or mechanical ablation followed by secondary ionization"

Laser

"Two-step techniques involving laser desorption/ablation followed by secondary ionization"

Acoustic

"Two-step acoustic desorption methods"

Multimode

"Multimode techniques involving two of the principles in previous categories"

Other

"One-of-a-kind techniques that do not fit into previous categories"

References