Chemical ionization: Difference between revisions

From Mass Spec Terms
Orange Book cat case, Replaced: == Orange Book entry == ‚Üí <!-- Orange Book -->, == Gold Book entry == ‚Üí <!-- Gold Book -->, using AWB
No edit summary
Line 2: Line 2:
Formation of a new ion in the gas phase by the reaction of a neutral species with an ion. The process may involve transfer of an electron, a proton or other charged species between the reactants.  
Formation of a new ion in the gas phase by the reaction of a neutral species with an ion. The process may involve transfer of an electron, a proton or other charged species between the reactants.  


Note 1: When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term [[negative ion chemical ionization]] should be used.  
'''Note 1''': When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term [[negative ion chemical ionization]] should be used.  


Note 2: this term is not synonymous with [[chemi-ionization]].
'''Note 2''': this term is not synonymous with [[chemi-ionization]].
}}
}}


Line 30: Line 30:
== External links ==
== External links ==
*[http://www.asms.org/whatisms/index.html ASMS What is MS?]: [http://www.asms.org/whatisms/p11.html What Other Techniques are used to Produce Ions?]
*[http://www.asms.org/whatisms/index.html ASMS What is MS?]: [http://www.asms.org/whatisms/p11.html What Other Techniques are used to Produce Ions?]
*[[Wikipedia:Chemical ionization]]


[[Category:Ionization]]
[[Category:Ionization]]
{{DEFAULTSORT:Chemical Ionization}}
{{DEFAULTSORT:Chemical Ionization}}
[[Category:Orange Book term]]
[[Category:Orange Book term]]

Revision as of 14:53, 18 July 2009

Obsolete Template

Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023)

Chemical ionization

Describes the process whereby new ionized species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, a proton or other charged species between the reactants. When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term negative ion chemical ionization should be used. Note that this term is not synonymous with chemi-ionization, nor with negative chemical ionization.

IUPAC 1997 Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Chemical ionization

http://goldbook.iupac.org/C01026.html

This concerns the process whereby new ionization species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, proton or other charged species between the reactants. When a positive ion results from chemical ionization, the term may be used without qualification. When a negative ion is involved, the term negative ion chemical ionization should be used; note that negative ion formation by attachment of a free electron does not fall within this definition. Chemical ionization and chemi-ionization are two terms which should not be used interchangeably. See: electron attachment

See also: chemi-ionization

Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1547

Orange Book, p. 204

PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2179

IUPAC Gold Book
Index of Gold Book Terms


External links