Atmospheric pressure ionization: Difference between revisions
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Atmospheric pressure ionization is any process in which ions are formed from atoms or molecules at atmospheric pressure. Note that atmospheric pressure ionization should not be used as a synonym for atmospheric pressure chemical ionization. | |||
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#D.I. Carroll, I. Dzidic, R.N. Stillwell, K.D. Haegele, E.C. Horning, Anal. Chem. 47 (1975) 2369. | |||
#E. Rosenberg, J. Chromatogr., A 1000 (2003) 841. | |||
#J.F.J. Todd, Int. J. Mass Spectrom. Ion Processes 142 (1995) 211.}} | |||
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Page 11: "...when used as an abbreviation for [[atmospheric pressure chemical ionization]]..." | Page 11: "...when used as an abbreviation for [[atmospheric pressure chemical ionization]]..." | ||
Revision as of 22:49, 2 April 2010
Obsolete Template
Gold Book
| GOLD BOOK DEFINITION
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). |
| Atmospheric pressure ionization |
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atmospheric pressure ionization (obsolete) in mass spectrometry An ambiguous term; in essence, it is used to describe chemical ionization at atmospheric pressure. It is recommended that use of the term be discontinued. Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1547 |
| IUPAC Gold Book |
| Index of Gold Book Terms |
| ASMS TERMS AND DEFINITIONS POSTER ENTRY |
| Atmospheric pressure ionization |
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Ionization technique(s) that occur at atmospheric pressure. Specific API ionization techniques include electrospray, pneumatically assisted electrospray and atmospheric pressure chemical ionization and is often used to couple LC to MS. A reader???????????s comment: Atmospheric pressure ionization (API) should remain a general term, for any form of ionization at atmosphere. The definition given is specific for chemical ionization at atmosphere. The definition given should be for a separate term, atmospheric pressure chemical ionization (APCI). This was merely the first atmospheric pressure ionization means that was commercialized. API would then properly include, electrospray (ESI), APCI, Ionspray (a coined term, and more generally this is pneumatically-assisted electrospray), and flame ionization (in some of the early papers on API this was the mode of ionization). Lots of others have been tried including microwave, etc. |
| ASMS Terms and Definitions Poster |
