Radical ion

From Mass Spec Terms
Revision as of 14:42, 3 February 2005 by Mneberlin (talk | contribs)

An ion, either a cation or anion, containing an unpaired electron. The unpaired electron is denoted by a superscript dot alongside the superscript symbol for charge, such as for SF6 -?????????????????????. Radical ions with more than one charge and/or more than one unpaired electron these are denoted as X(2+) (2?????????????????????) or X(2?????????????????????) (2+).Unless the positions of unpaired spin and charge can be associated with specific atoms, superscript dot and charge designations should be placed in the order +1????????????????????? or -????????????????????? e.g. C3H6+1?????????????????????.