Charge-transfer reaction (in mass spectrometry)

Obsolete Template

Orange Book entry

Orange Book

ORANGE BOOK DEFINITION IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023)
Charge-transfer reaction (in mass spectrometry)
An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows: M2+ + X → M+ + X+ (Partial charge transfer) M+ + X → M2+ + X + e (Charge stripping) M- + X → M+ + X + 2e (Charge stripping & charge inversion) These are all ion/neutral species reactions and also charge permutation reactions.
IUPAC 1997 Orange Book Chapter 12
Index of Orange Book Terms

See also

• Charge Exchange Reaction
• Charge-Induced Fragmentation
• Charge Inversion Reaction
• Charge Permutation Reaction
• Charge-Remote Fragmentation
• Charge Stripping Reaction